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	<title>The Residual Polarization Model - Revision history</title>
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	<updated>2026-04-08T08:11:49Z</updated>
	<subtitle>Revision history for this page on the wiki</subtitle>
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	<entry>
		<id>http://localhost/mediawiki/index.php?title=The_Residual_Polarization_Model&amp;diff=838&amp;oldid=prev</id>
		<title>Jess at 18:30, 17 September 2022</title>
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		<updated>2022-09-17T18:30:51Z</updated>

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				&lt;td colspan=&quot;2&quot; style=&quot;background-color: #fff; color: #202122; text-align: center;&quot;&gt;← Older revision&lt;/td&gt;
				&lt;td colspan=&quot;2&quot; style=&quot;background-color: #fff; color: #202122; text-align: center;&quot;&gt;Revision as of 18:30, 17 September 2022&lt;/td&gt;
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  &lt;td class=&quot;diff-context diff-side-deleted&quot;&gt;&lt;div&gt;Only the real part of the polarization is shown.  &lt;/div&gt;&lt;/td&gt;
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  &lt;td class=&quot;diff-context diff-side-added&quot;&gt;&lt;div&gt;Only the real part of the polarization is shown.  &lt;/div&gt;&lt;/td&gt;
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&lt;/table&gt;</summary>
		<author><name>Jess</name></author>
	</entry>
	<entry>
		<id>http://localhost/mediawiki/index.php?title=The_Residual_Polarization_Model&amp;diff=590&amp;oldid=prev</id>
		<title>WikiSysop: /* Phase Shifts in Precession Experiments */</title>
		<link rel="alternate" type="text/html" href="http://localhost/mediawiki/index.php?title=The_Residual_Polarization_Model&amp;diff=590&amp;oldid=prev"/>
		<updated>2022-08-29T17:27:01Z</updated>

		<summary type="html">&lt;p&gt;&lt;span dir=&quot;auto&quot;&gt;&lt;span class=&quot;autocomment&quot;&gt;Phase Shifts in Precession Experiments&lt;/span&gt;&lt;/span&gt;&lt;/p&gt;
&lt;table class=&quot;diff diff-contentalign-left diff-editfont-monospace&quot; data-mw=&quot;interface&quot;&gt;
				&lt;col class=&quot;diff-marker&quot; /&gt;
				&lt;col class=&quot;diff-content&quot; /&gt;
				&lt;col class=&quot;diff-marker&quot; /&gt;
				&lt;col class=&quot;diff-content&quot; /&gt;
				&lt;tr class=&quot;diff-title&quot; lang=&quot;en&quot;&gt;
				&lt;td colspan=&quot;2&quot; style=&quot;background-color: #fff; color: #202122; text-align: center;&quot;&gt;← Older revision&lt;/td&gt;
				&lt;td colspan=&quot;2&quot; style=&quot;background-color: #fff; color: #202122; text-align: center;&quot;&gt;Revision as of 17:27, 29 August 2022&lt;/td&gt;
				&lt;/tr&gt;&lt;tr&gt;
  &lt;td colspan=&quot;2&quot; class=&quot;diff-lineno&quot;&gt;Line 287:&lt;/td&gt;
  &lt;td colspan=&quot;2&quot; class=&quot;diff-lineno&quot;&gt;Line 287:&lt;/td&gt;
&lt;/tr&gt;
&lt;tr&gt;
  &lt;td class=&quot;diff-marker&quot;&gt;&lt;/td&gt;
  &lt;td class=&quot;diff-context diff-side-deleted&quot;&gt;&lt;div&gt;is unchanged, but since &amp;lt;math&amp;gt;\kappa_i&amp;lt;/math&amp;gt; and/or &amp;lt;math&amp;gt;\kappa_f&amp;lt;/math&amp;gt; &lt;/div&gt;&lt;/td&gt;
  &lt;td class=&quot;diff-marker&quot;&gt;&lt;/td&gt;
  &lt;td class=&quot;diff-context diff-side-added&quot;&gt;&lt;div&gt;is unchanged, but since &amp;lt;math&amp;gt;\kappa_i&amp;lt;/math&amp;gt; and/or &amp;lt;math&amp;gt;\kappa_f&amp;lt;/math&amp;gt; &lt;/div&gt;&lt;/td&gt;
&lt;/tr&gt;
&lt;tr&gt;
  &lt;td class=&quot;diff-marker&quot;&gt;&lt;/td&gt;
  &lt;td class=&quot;diff-context diff-side-deleted&quot;&gt;&lt;div&gt;are complex, the prefactors in front of the time-dependent &lt;/div&gt;&lt;/td&gt;
  &lt;td class=&quot;diff-marker&quot;&gt;&lt;/td&gt;
  &lt;td class=&quot;diff-context diff-side-added&quot;&gt;&lt;div&gt;are complex, the prefactors in front of the time-dependent &lt;/div&gt;&lt;/td&gt;
&lt;/tr&gt;
&lt;tr&gt;
  &lt;td class=&quot;diff-marker&quot; data-marker=&quot;−&quot;&gt;&lt;/td&gt;
  &lt;td class=&quot;diff-deletedline diff-side-deleted&quot;&gt;&lt;div&gt;terms are also complex and therefore include &amp;lt;i&amp;gt;phase shifts&lt;del class=&quot;diffchange diffchange-inline&quot;&gt;}&lt;/del&gt;.  &lt;/div&gt;&lt;/td&gt;
  &lt;td class=&quot;diff-marker&quot; data-marker=&quot;+&quot;&gt;&lt;/td&gt;
  &lt;td class=&quot;diff-addedline diff-side-added&quot;&gt;&lt;div&gt;terms are also complex and therefore include &amp;lt;i&amp;gt;phase shifts&lt;ins class=&quot;diffchange diffchange-inline&quot;&gt;&amp;lt;/i&amp;gt;&lt;/ins&gt;.  &lt;/div&gt;&lt;/td&gt;
&lt;/tr&gt;
&lt;tr&gt;
  &lt;td class=&quot;diff-marker&quot;&gt;&lt;/td&gt;
  &lt;td class=&quot;diff-context diff-side-deleted&quot;&gt;&lt;div&gt;Although this extension is formally trivial, it introduces &lt;/div&gt;&lt;/td&gt;
  &lt;td class=&quot;diff-marker&quot;&gt;&lt;/td&gt;
  &lt;td class=&quot;diff-context diff-side-added&quot;&gt;&lt;div&gt;Although this extension is formally trivial, it introduces &lt;/div&gt;&lt;/td&gt;
&lt;/tr&gt;
&lt;tr&gt;
  &lt;td class=&quot;diff-marker&quot;&gt;&lt;/td&gt;
  &lt;td class=&quot;diff-context diff-side-deleted&quot;&gt;&lt;div&gt;a wealth of additional phenomenology.  &lt;/div&gt;&lt;/td&gt;
  &lt;td class=&quot;diff-marker&quot;&gt;&lt;/td&gt;
  &lt;td class=&quot;diff-context diff-side-added&quot;&gt;&lt;div&gt;a wealth of additional phenomenology.  &lt;/div&gt;&lt;/td&gt;
&lt;/tr&gt;
&lt;/table&gt;</summary>
		<author><name>WikiSysop</name></author>
	</entry>
	<entry>
		<id>http://localhost/mediawiki/index.php?title=The_Residual_Polarization_Model&amp;diff=589&amp;oldid=prev</id>
		<title>WikiSysop: /* Delayed Muonium Formation */</title>
		<link rel="alternate" type="text/html" href="http://localhost/mediawiki/index.php?title=The_Residual_Polarization_Model&amp;diff=589&amp;oldid=prev"/>
		<updated>2022-08-29T17:25:48Z</updated>

		<summary type="html">&lt;p&gt;&lt;span dir=&quot;auto&quot;&gt;&lt;span class=&quot;autocomment&quot;&gt;Delayed Muonium Formation&lt;/span&gt;&lt;/span&gt;&lt;/p&gt;
&lt;table class=&quot;diff diff-contentalign-left diff-editfont-monospace&quot; data-mw=&quot;interface&quot;&gt;
				&lt;col class=&quot;diff-marker&quot; /&gt;
				&lt;col class=&quot;diff-content&quot; /&gt;
				&lt;col class=&quot;diff-marker&quot; /&gt;
				&lt;col class=&quot;diff-content&quot; /&gt;
				&lt;tr class=&quot;diff-title&quot; lang=&quot;en&quot;&gt;
				&lt;td colspan=&quot;2&quot; style=&quot;background-color: #fff; color: #202122; text-align: center;&quot;&gt;← Older revision&lt;/td&gt;
				&lt;td colspan=&quot;2&quot; style=&quot;background-color: #fff; color: #202122; text-align: center;&quot;&gt;Revision as of 17:25, 29 August 2022&lt;/td&gt;
				&lt;/tr&gt;&lt;tr&gt;
  &lt;td colspan=&quot;2&quot; class=&quot;diff-lineno&quot;&gt;Line 351:&lt;/td&gt;
  &lt;td colspan=&quot;2&quot; class=&quot;diff-lineno&quot;&gt;Line 351:&lt;/td&gt;
&lt;/tr&gt;
&lt;tr&gt;
  &lt;td class=&quot;diff-marker&quot;&gt;&lt;/td&gt;
  &lt;td class=&quot;diff-context diff-side-deleted&quot;&gt;&lt;div&gt;=== Delayed Muonium Formation ===&lt;/div&gt;&lt;/td&gt;
  &lt;td class=&quot;diff-marker&quot;&gt;&lt;/td&gt;
  &lt;td class=&quot;diff-context diff-side-added&quot;&gt;&lt;div&gt;=== Delayed Muonium Formation ===&lt;/div&gt;&lt;/td&gt;
&lt;/tr&gt;
&lt;tr&gt;
  &lt;td class=&quot;diff-marker&quot;&gt;&lt;/td&gt;
  &lt;td class=&quot;diff-context diff-side-deleted&quot;&gt;&lt;br /&gt;&lt;/td&gt;
  &lt;td class=&quot;diff-marker&quot;&gt;&lt;/td&gt;
  &lt;td class=&quot;diff-context diff-side-added&quot;&gt;&lt;br /&gt;&lt;/td&gt;
&lt;/tr&gt;
&lt;tr&gt;
  &lt;td class=&quot;diff-marker&quot; data-marker=&quot;−&quot;&gt;&lt;/td&gt;
  &lt;td class=&quot;diff-deletedline diff-side-deleted&quot;&gt;&lt;div&gt;The opposite situation (in a sense) applies in some insulators and &lt;del class=&quot;diffchange diffchange-inline&quot;&gt;semicondustors&lt;/del&gt; &lt;/div&gt;&lt;/td&gt;
  &lt;td class=&quot;diff-marker&quot; data-marker=&quot;+&quot;&gt;&lt;/td&gt;
  &lt;td class=&quot;diff-addedline diff-side-added&quot;&gt;&lt;div&gt;The opposite situation (in a sense) applies in some insulators and &lt;ins class=&quot;diffchange diffchange-inline&quot;&gt;semiconductors&lt;/ins&gt; &lt;/div&gt;&lt;/td&gt;
&lt;/tr&gt;
&lt;tr&gt;
  &lt;td class=&quot;diff-marker&quot;&gt;&lt;/td&gt;
  &lt;td class=&quot;diff-context diff-side-deleted&quot;&gt;&lt;div&gt;where the muon ensemble differentiates initially into &lt;/div&gt;&lt;/td&gt;
  &lt;td class=&quot;diff-marker&quot;&gt;&lt;/td&gt;
  &lt;td class=&quot;diff-context diff-side-added&quot;&gt;&lt;div&gt;where the muon ensemble differentiates initially into &lt;/div&gt;&lt;/td&gt;
&lt;/tr&gt;
&lt;tr&gt;
  &lt;td class=&quot;diff-marker&quot;&gt;&lt;/td&gt;
  &lt;td class=&quot;diff-context diff-side-deleted&quot;&gt;&lt;div&gt;a &amp;lt;i&amp;gt;stable&amp;lt;/i&amp;gt; diamagnetic fraction &amp;lt;math&amp;gt;f_D&amp;lt;/math&amp;gt;, &lt;/div&gt;&lt;/td&gt;
  &lt;td class=&quot;diff-marker&quot;&gt;&lt;/td&gt;
  &lt;td class=&quot;diff-context diff-side-added&quot;&gt;&lt;div&gt;a &amp;lt;i&amp;gt;stable&amp;lt;/i&amp;gt; diamagnetic fraction &amp;lt;math&amp;gt;f_D&amp;lt;/math&amp;gt;, &lt;/div&gt;&lt;/td&gt;
&lt;/tr&gt;
&lt;/table&gt;</summary>
		<author><name>WikiSysop</name></author>
	</entry>
	<entry>
		<id>http://localhost/mediawiki/index.php?title=The_Residual_Polarization_Model&amp;diff=557&amp;oldid=prev</id>
		<title>WikiSysop: Created page with &quot;Relaxonomy --&gt; here ----  A wide class of &amp;micro;SR problems correspond to the following  simple picture: the muon spin evolves with time in an initial  state &lt;math&gt;\vert...&quot;</title>
		<link rel="alternate" type="text/html" href="http://localhost/mediawiki/index.php?title=The_Residual_Polarization_Model&amp;diff=557&amp;oldid=prev"/>
		<updated>2022-08-20T01:26:45Z</updated>

		<summary type="html">&lt;p&gt;Created page with &amp;quot;&lt;a href=&quot;/mediawiki/index.php/Relaxonomy&quot; title=&quot;Relaxonomy&quot;&gt;Relaxonomy&lt;/a&gt; --&amp;gt; here ----  A wide class of µSR problems correspond to the following  simple picture: the muon spin evolves with time in an initial  state &amp;lt;math&amp;gt;\vert...&amp;quot;&lt;/p&gt;
&lt;p&gt;&lt;b&gt;New page&lt;/b&gt;&lt;/p&gt;&lt;div&gt;[[Relaxonomy]] --&amp;gt; here&lt;br /&gt;
----&lt;br /&gt;
&lt;br /&gt;
A wide class of &amp;amp;micro;SR problems correspond to the following &lt;br /&gt;
simple picture: the muon spin evolves with time in an initial &lt;br /&gt;
state &amp;lt;math&amp;gt;\vert i \rangle&amp;lt;/math&amp;gt; until time &amp;lt;math&amp;gt;t&amp;#039;&amp;lt;/math&amp;gt;, &lt;br /&gt;
when it makes an abrupt transition &lt;br /&gt;
to state &amp;lt;math&amp;gt;\vert f \rangle&amp;lt;/math&amp;gt;, in which it evolves subsequently.  &lt;br /&gt;
The transition times may in principle have any distribution &lt;br /&gt;
&amp;lt;math&amp;gt;D(t&amp;#039;)&amp;lt;/math&amp;gt; such that &amp;lt;math&amp;gt;\int_0^\infty D(t&amp;#039;) \, dt&amp;#039; &lt;br /&gt;
\; = \; 1 &amp;lt;/math&amp;gt;, &lt;br /&gt;
but the mathematics will be simplest in cases where &lt;br /&gt;
&amp;lt;math&amp;gt;D(t&amp;#039;) = \Lambda \exp(-\Lambda t&amp;#039;)&amp;lt;/math&amp;gt;  -- that is, where &lt;br /&gt;
the transition occurs at a time that is distributed exponentially &lt;br /&gt;
with a &amp;quot;reaction rate&amp;quot; &amp;lt;math&amp;gt;\Lambda&amp;lt;/math&amp;gt;.  &lt;br /&gt;
This picture can be extended to two-transition and even &lt;br /&gt;
repetitive-transition cases, but the salient features &lt;br /&gt;
emerge most vividly from the simplest cases.  &lt;br /&gt;
&lt;br /&gt;
----&lt;br /&gt;
&lt;br /&gt;
Because it was first used to describe the observable diamagnetic &lt;br /&gt;
muon polarization &amp;lt;math&amp;gt;\vert f \rangle \equiv \mu_D&amp;lt;/math&amp;gt; &lt;br /&gt;
following chemical reaction &lt;br /&gt;
of muonium &amp;lt;math&amp;gt;\vert i \rangle \equiv &amp;lt;/math&amp;gt; Mu &lt;br /&gt;
in weak transverse magnetic fields (wTF), &lt;br /&gt;
I call this picture the &amp;quot;Residual Polarization Model.&amp;quot;  &lt;br /&gt;
Since it can also be used to describe situations in which &lt;br /&gt;
the time-dependence of the muon polarization in the &lt;br /&gt;
initial state is observable, this nomenclature is logically imperfect; &lt;br /&gt;
but it does have the desired connotations, so I will use it.  &lt;br /&gt;
&lt;br /&gt;
First let me be fairly formal and rigourous to show how general &lt;br /&gt;
this formulation might be; then I will revert to simple cases &lt;br /&gt;
and build up slowly to the more elaborate.  &lt;br /&gt;
&lt;br /&gt;
== Formalism ==&lt;br /&gt;
&lt;br /&gt;
The symbols &amp;lt;math&amp;gt;\vert i \rangle&amp;lt;/math&amp;gt; and &amp;lt;math&amp;gt;\vert f \rangle&amp;lt;/math&amp;gt; &lt;br /&gt;
do not refer to energy eigenkets, &lt;br /&gt;
of course, but to &amp;quot;superstates&amp;quot; -- generalizations of the &lt;br /&gt;
notion of a &amp;quot;state&amp;quot; in which &amp;lt;math&amp;gt;\vert i \rangle&amp;lt;/math&amp;gt; could refer to something &lt;br /&gt;
as complicated as a &amp;quot;diffusing muonium atom&amp;quot; &amp;lt;i&amp;gt;as long as &lt;br /&gt;
we can get away with treating its spin polarization &lt;br /&gt;
as a well-defined funtion of time&amp;lt;/i&amp;gt;.  &lt;br /&gt;
Similarly with &amp;lt;math&amp;gt;\vert f \rangle&amp;lt;/math&amp;gt;, whose polarization would evolve &lt;br /&gt;
in a well-defined manner if muons started in this state at &amp;lt;math&amp;gt;t=0&amp;lt;/math&amp;gt;.  &lt;br /&gt;
The term &amp;quot;spin polarization&amp;quot; need not refer only to the &lt;br /&gt;
&amp;lt;i&amp;gt;muon&amp;lt;/i&amp;gt; polarization &amp;lt;math&amp;gt;\vec{P}_\mu(t)&amp;lt;/math&amp;gt;, much less &lt;br /&gt;
its scalar component &amp;lt;math&amp;gt;P^\mu_j(t)&amp;lt;/math&amp;gt; along the &amp;lt;math&amp;gt;j^{\rm th}&amp;lt;/math&amp;gt; axis; &lt;br /&gt;
for the familiar case &amp;lt;math&amp;gt;\vert i \rangle \equiv&amp;lt;/math&amp;gt; Mu, for instance, the &lt;br /&gt;
initial polarization of the muon is subsequently &amp;lt;i&amp;gt;shared&amp;lt;/i&amp;gt; between &lt;br /&gt;
muon, electron and &amp;quot;off-diagonal&amp;quot; degrees of freedom of &lt;br /&gt;
the spin density matrix.  Whether all these need to be &amp;quot;tracked&amp;quot; &lt;br /&gt;
through the &amp;quot;reaction&amp;quot; depends, of course, on whether the &lt;br /&gt;
other spin degrees of freedom are passed coherently to &lt;br /&gt;
analogous ones in &amp;lt;math&amp;gt;\vert f \rangle&amp;lt;/math&amp;gt;, in which case their values at &lt;br /&gt;
the time of reaction affect the subsequent evolution.  &lt;br /&gt;
This can get messy, and ought probably to be formulated &lt;br /&gt;
in terms of the density matrix itself, but I will stick with &lt;br /&gt;
a phenomenological formalism where &amp;lt;math&amp;gt;\Pi(t)&amp;lt;/math&amp;gt; represents &lt;br /&gt;
&amp;quot;the spin polarization&amp;quot; in the relevant superstate, &lt;br /&gt;
however many components or degrees of freedom it must &lt;br /&gt;
encompass to satisfy the requirements of the problem.  &lt;br /&gt;
&lt;br /&gt;
Hmmm...  This has to be done with quantum states and &lt;br /&gt;
operators for the general case.  Later.&lt;br /&gt;
&lt;br /&gt;
== Simple Exponentially Relaxing States ==&lt;br /&gt;
&lt;br /&gt;
We begin with what might be considered the trivial case: &lt;br /&gt;
plain exponential muon relaxation in LF geometry so that only &lt;br /&gt;
the longitudinal component of the muon polarization matters &lt;br /&gt;
and the whole problem is a real, scalar one.  Then &lt;br /&gt;
&amp;lt;math&amp;gt;\vert i \rangle&amp;lt;/math&amp;gt; has a time dependent polarization &lt;br /&gt;
&amp;lt;math&amp;gt;P_i(t) = e^{-\lambda_i t}&amp;lt;/math&amp;gt; &lt;br /&gt;
and &amp;lt;math&amp;gt;\vert f \rangle&amp;lt;/math&amp;gt; would have &lt;br /&gt;
&amp;lt;math&amp;gt;P_f(t) = e^{-\lambda_f t}&amp;lt;/math&amp;gt; if it started &lt;br /&gt;
fully polarized at &amp;lt;math&amp;gt;t=0&amp;lt;/math&amp;gt;.  &lt;br /&gt;
&lt;br /&gt;
The depolarization rate in state &amp;lt;math&amp;gt;\vert i \rangle&amp;lt;/math&amp;gt; is &amp;lt;math&amp;gt;\lambda_i&amp;lt;/math&amp;gt;.  &lt;br /&gt;
The depolarization rate in state &amp;lt;math&amp;gt;\vert f \rangle&amp;lt;/math&amp;gt; is &amp;lt;math&amp;gt;\lambda_f&amp;lt;/math&amp;gt;.  &lt;br /&gt;
For generality we may let a fraction &amp;lt;math&amp;gt;(1-q)&amp;lt;/math&amp;gt; of the &lt;br /&gt;
polarization be &amp;quot;abruptly&amp;quot; lost at the time of transition &lt;br /&gt;
between &amp;lt;math&amp;gt;\vert i \rangle&amp;lt;/math&amp;gt; and &amp;lt;math&amp;gt;\vert f \rangle&amp;lt;/math&amp;gt; &lt;br /&gt;
-- for muonium formation in low &lt;br /&gt;
field, this fraction would be effectively 50%.  &lt;br /&gt;
(If &amp;lt;math&amp;gt;\Lambda &amp;gt; \sim 4.463&amp;lt;/math&amp;gt; GHz, this approximation is invalid.)  &lt;br /&gt;
If &amp;lt;math&amp;gt;\vert i \rangle \to \vert f \rangle&amp;lt;/math&amp;gt; at time &amp;lt;math&amp;gt;t&amp;#039;&amp;lt;/math&amp;gt; with &lt;br /&gt;
&amp;lt;math&amp;gt;D(t&amp;#039;) \; = \; \Lambda \, e^{-\Lambda \, t&amp;#039;}&amp;lt;/math&amp;gt; &lt;br /&gt;
so that &amp;lt;math&amp;gt;\int_0^\infty D(t&amp;#039;) \, dt&amp;#039; = 1 &amp;lt;/math&amp;gt;, we have &lt;br /&gt;
&amp;lt;center&amp;gt;&amp;lt;math&amp;gt;&lt;br /&gt;
 P(t) = &lt;br /&gt;
 e^{-\Lambda t} \cdot e^{-\lambda_i t} + q \Lambda \, \int_0^t &lt;br /&gt;
 e^{-\lambda_i t&amp;#039;} \cdot e^{-\lambda_f(t-t&amp;#039;)} \cdot e^{-\Lambda t&amp;#039;} dt&amp;#039; &lt;br /&gt;
&amp;lt;/math&amp;gt;&lt;br /&gt;
&amp;lt;math&amp;gt;&lt;br /&gt;
 = e^{-(\Lambda + \lambda_i)t} + q \Lambda \, e^{-\lambda_f t} &lt;br /&gt;
 \int_0^t e^{-(\Lambda + \lambda_i - \lambda_f)t&amp;#039;} dt&amp;#039; &lt;br /&gt;
&amp;lt;/math&amp;gt;&lt;br /&gt;
&amp;lt;math&amp;gt;&lt;br /&gt;
 = e^{-(\Lambda + \lambda_i)t} - &lt;br /&gt;
 q {\Lambda \over \Lambda + \lambda_i - \lambda_f} \, e^{-\lambda_f t}  &lt;br /&gt;
 \int_0^{-(\Lambda + \lambda_i - \lambda_f)t} e^u \, du&lt;br /&gt;
&amp;lt;/math&amp;gt;&lt;br /&gt;
&amp;lt;math&amp;gt;&lt;br /&gt;
 = e^{-(\Lambda + \lambda_i)t} - &lt;br /&gt;
 q {\Lambda \over \Lambda + \lambda_i - \lambda_f} \, e^{-\lambda_f t} &lt;br /&gt;
 \left[e^{-(\Lambda + \lambda_i - \lambda_f)t} - 1 \right] &lt;br /&gt;
&amp;lt;/math&amp;gt;&lt;br /&gt;
&amp;lt;math&amp;gt;&lt;br /&gt;
 = \; e^{-(\Lambda + \lambda_i)t} - &lt;br /&gt;
 q {\Lambda \over \Lambda + \lambda_i - \lambda_f} &lt;br /&gt;
 \left[e^{-(\Lambda + \lambda_i)t} - e^{-\lambda_f t} \right] &lt;br /&gt;
&amp;lt;/math&amp;gt;&amp;lt;/center&amp;gt;&lt;br /&gt;
or&lt;br /&gt;
&amp;lt;center&amp;gt;&amp;lt;math&amp;gt;&lt;br /&gt;
 P(t) = \left[ 1 - q \left( {\Lambda \over \Lambda + \lambda_i - \lambda_f} \right) \right] e^{-(\Lambda + \lambda_i)t} &lt;br /&gt;
 + q \left( {\Lambda \over \Lambda + \lambda_i - \lambda_f} \right) e^{-\lambda_f t} . &lt;br /&gt;
&amp;lt;/math&amp;gt;&amp;lt;/center&amp;gt;&lt;br /&gt;
&lt;br /&gt;
For further reference, this is the &amp;lt;b&amp;gt;Rate Equation&amp;lt;/b&amp;gt; for this simple model.  &lt;br /&gt;
For &amp;lt;math&amp;gt;q=1&amp;lt;/math&amp;gt; (no depolarization on transition) it becomes &lt;br /&gt;
&amp;lt;center&amp;gt;&amp;lt;math&amp;gt;&lt;br /&gt;
 P(t) = &lt;br /&gt;
 \left( {\lambda_i - \lambda_f \over \Lambda + \lambda_i - \lambda_f} \right) e^{-(\Lambda + \lambda_i)t} &lt;br /&gt;
 + \left( {\Lambda \over \Lambda + \lambda_i - \lambda_f} \right) e^{-\lambda_f t} &lt;br /&gt;
&amp;lt;/math&amp;gt;&amp;lt;/center&amp;gt;&lt;br /&gt;
&lt;br /&gt;
=== Example: No Depolarization in Initial State ===&lt;br /&gt;
&lt;br /&gt;
Here we have &amp;lt;math&amp;gt;\lambda_i = 0&amp;lt;/math&amp;gt; and &amp;lt;math&amp;gt;\lambda_f = \lambda&amp;lt;/math&amp;gt;, giving &lt;br /&gt;
&amp;lt;center&amp;gt;&amp;lt;math&amp;gt;&lt;br /&gt;
 P(t) = &lt;br /&gt;
 \left[ 1 - q \left( {\lambda \over \Lambda - \lambda} \right) \right] e^{-\Lambda t} &lt;br /&gt;
 + q \left( {\Lambda \over \Lambda - \lambda} \right) e^{-\lambda t} &lt;br /&gt;
&amp;lt;/math&amp;gt;&amp;lt;/center&amp;gt;&lt;br /&gt;
or, for &amp;lt;math&amp;gt;q=1&amp;lt;/math&amp;gt;, &lt;br /&gt;
&amp;lt;center&amp;gt;&amp;lt;math&amp;gt;&lt;br /&gt;
 P(t) = \left( {\lambda \over \lambda - \Lambda} \right) e^{-\Lambda t} &lt;br /&gt;
 + \left( {\Lambda \over \Lambda - \lambda} \right) e^{-\lambda t} &lt;br /&gt;
&amp;lt;/math&amp;gt;&amp;lt;/center&amp;gt;&lt;br /&gt;
Now, this may look unconvincing, since it &amp;lt;i&amp;gt;appears&amp;lt;/i&amp;gt; to &lt;br /&gt;
diverge as &amp;lt;math&amp;gt;\Lambda \to \lambda&amp;lt;/math&amp;gt;.  However, appearances are deceiving!  &lt;br /&gt;
The reader may wish to show as an exercise that there is no anomaly &lt;br /&gt;
at &amp;lt;math&amp;gt;\Lambda = \lambda&amp;lt;/math&amp;gt;; I will let the computer speak for itself.  &lt;br /&gt;
&lt;br /&gt;
Some sample relaxation functions from this formula &lt;br /&gt;
are shown in Fig. 1.  &lt;br /&gt;
&lt;br /&gt;
Note the similarity of the &amp;lt;math&amp;gt;q=1&amp;lt;/math&amp;gt; relaxation functions to &lt;br /&gt;
the widely overused &amp;quot;stretched exponential&amp;quot; function &lt;br /&gt;
&amp;lt;math&amp;gt;G_{\rm SE}(t) = \exp(-[\lambda t]^\beta/\beta)&amp;lt;/math&amp;gt;&lt;br /&gt;
(shown in red for &amp;lt;math&amp;gt;\lambda=1&amp;lt;/math&amp;gt; &amp;amp;micro;s&amp;lt;math&amp;gt;^{-1}&amp;lt;/math&amp;gt; and &amp;lt;math&amp;gt;\beta=1.5&amp;lt;/math&amp;gt;).  &lt;br /&gt;
&lt;br /&gt;
&amp;lt;center&amp;gt;&lt;br /&gt;
[[Image:ResPol_q1_Ri0_Rf1.png|600px|inline image (click to see full size)]]&lt;br /&gt;
{| width=&amp;quot;80%&amp;quot; &lt;br /&gt;
! align=&amp;quot;left&amp;quot; |&lt;br /&gt;
Figure &amp;lt;b&amp;gt;1a&amp;lt;/b&amp;gt;: &lt;br /&gt;
Depolarization functions for &amp;lt;math&amp;gt;q=1&amp;lt;/math&amp;gt;  and a relaxation rate of &lt;br /&gt;
&amp;lt;math&amp;gt;\lambda = 1&amp;lt;/math&amp;gt; &amp;amp;micro;s&amp;lt;math&amp;gt;^{-1}&amp;lt;/math&amp;gt; &lt;br /&gt;
in the &amp;lt;i&amp;gt;final&amp;lt;/i&amp;gt; state with &amp;lt;i&amp;gt;no&amp;lt;/i&amp;gt; relaxation in the &lt;br /&gt;
&amp;lt;i&amp;gt;initial&amp;lt;/i&amp;gt; state, for various choices of the &amp;quot;reaction&amp;quot; rate  &lt;br /&gt;
&amp;lt;math&amp;gt;\Lambda = \{0.5, 1.01, 3, 10, 100\} &amp;lt;/math&amp;gt; &amp;amp;micro;s&amp;lt;math&amp;gt;^{-1}&amp;lt;/math&amp;gt;.  &lt;br /&gt;
|}&lt;br /&gt;
&lt;br /&gt;
[[Image:ResPol_q.5_Ri0_Rf1.png|600px|inline image (click to see full size)]]&lt;br /&gt;
{| width=&amp;quot;80%&amp;quot; &lt;br /&gt;
! align=&amp;quot;left&amp;quot; |&lt;br /&gt;
Figure &amp;lt;b&amp;gt;1b&amp;lt;/b&amp;gt;: &lt;br /&gt;
Depolarization functions for &amp;lt;math&amp;gt;q=0.5&amp;lt;/math&amp;gt; and other parameters the same as in Fig. &amp;lt;b&amp;gt;1a&amp;lt;/b&amp;gt;.&lt;br /&gt;
|}&lt;br /&gt;
&lt;br /&gt;
&amp;lt;/center&amp;gt;&lt;br /&gt;
&lt;br /&gt;
=== Example: No Depolarization in Final State ===&lt;br /&gt;
&lt;br /&gt;
Here we have &amp;lt;math&amp;gt;\lambda_f = 0&amp;lt;/math&amp;gt; and &amp;lt;math&amp;gt;\lambda_i = \lambda&amp;lt;/math&amp;gt;, giving &lt;br /&gt;
&lt;br /&gt;
&amp;lt;center&amp;gt;&amp;lt;math&amp;gt;&lt;br /&gt;
 P(t) = q \left( {\Lambda \over \Lambda + \lambda} \right) + &lt;br /&gt;
 \left[1 - q \left( {\Lambda \over \Lambda + \lambda} \right) \right] &lt;br /&gt;
 e^{-(\Lambda + \lambda)t} &lt;br /&gt;
&amp;lt;/math&amp;gt;&amp;lt;/center&amp;gt;&lt;br /&gt;
or, for &amp;lt;math&amp;gt;q=1&amp;lt;/math&amp;gt;, &lt;br /&gt;
&amp;lt;center&amp;gt;&amp;lt;math&amp;gt;&lt;br /&gt;
 P(t) = { \Lambda \over \Lambda + \lambda } + &lt;br /&gt;
 {\lambda \over \Lambda + \lambda} e^{-(\Lambda + \lambda)t} &lt;br /&gt;
&amp;lt;/math&amp;gt;&amp;lt;/center&amp;gt;&lt;br /&gt;
&lt;br /&gt;
&amp;lt;center&amp;gt;&lt;br /&gt;
[[Image:ResPol_q1_Ri1_Rf0.png|600px|inline image (click to see full size)]]&lt;br /&gt;
{| width=&amp;quot;80%&amp;quot; &lt;br /&gt;
! align=&amp;quot;left&amp;quot; |&lt;br /&gt;
Figure &amp;lt;b&amp;gt;2a&amp;lt;/b&amp;gt;:&lt;br /&gt;
Depolarization functions for &amp;lt;math&amp;gt;q=1&amp;lt;/math&amp;gt; &lt;br /&gt;
with a relaxation rate of &amp;lt;math&amp;gt;\lambda = 1&amp;lt;/math&amp;gt; &amp;amp;micro;s&amp;lt;math&amp;gt;^{-1}&amp;lt;/math&amp;gt; &lt;br /&gt;
in the &amp;lt;i&amp;gt;initial&amp;lt;/i&amp;gt; state and &amp;lt;i&amp;gt;no&amp;lt;/i&amp;gt; relaxation in the &lt;br /&gt;
&amp;lt;i&amp;gt;final&amp;lt;/i&amp;gt; state, for various choices of the &amp;quot;reaction&amp;quot; rate &lt;br /&gt;
&amp;lt;math&amp;gt;\Lambda = \{0.1, 0.5, 1.01, 3, 10, 200\} &amp;lt;/math&amp;gt; &amp;amp;micro;s&amp;lt;math&amp;gt;^{-1}&amp;lt;/math&amp;gt;. &lt;br /&gt;
|}&amp;lt;/center&amp;gt;  &lt;br /&gt;
&amp;lt;center&amp;gt;&lt;br /&gt;
[[Image:ResPol_q.5_Ri1_Rf0.png|600px|inline image (click to see full size)]]&lt;br /&gt;
{| width=&amp;quot;80%&amp;quot; &lt;br /&gt;
! align=&amp;quot;left&amp;quot; |&lt;br /&gt;
Figure &amp;lt;b&amp;gt;2b&amp;lt;/b&amp;gt;:  &lt;br /&gt;
Depolarization functions for &amp;lt;math&amp;gt;q=0.5&amp;lt;/math&amp;gt; &lt;br /&gt;
and other parameters the same as in Fig. &amp;lt;b&amp;gt;2a&amp;lt;/b&amp;gt;. &lt;br /&gt;
|}&amp;lt;/center&amp;gt;&lt;br /&gt;
&lt;br /&gt;
== Application to Muonium Diffusion and Trapping ==&lt;br /&gt;
&lt;br /&gt;
Suppose Mu initially hops about in the host lattice at a rate &lt;br /&gt;
&amp;lt;math&amp;gt;\tau_i^{-1}&amp;lt;/math&amp;gt;, giving an &amp;quot;intrinsic&amp;quot; diffusion constant &lt;br /&gt;
&amp;lt;center&amp;gt;&amp;lt;math&amp;gt; &lt;br /&gt;
 D_i = {a^2 \over 4\tau_i} , &lt;br /&gt;
&amp;lt;/math&amp;gt;&amp;lt;/center&amp;gt;&lt;br /&gt;
where &amp;lt;math&amp;gt;a&amp;lt;/math&amp;gt; is the lattice constant.  &lt;br /&gt;
If the concentration of point defects (&amp;lt;i&amp;gt;e.g.&amp;lt;/i&amp;gt;, impurities) is &amp;lt;math&amp;gt;c&amp;lt;/math&amp;gt; &lt;br /&gt;
and the effective radius of their strain fields &lt;br /&gt;
(defined vaguely as the radius at which the energy difference &lt;br /&gt;
between sites due to the strain fields is sufficient to &lt;br /&gt;
slow down the Mu diffusion enough that I may regard Mu &lt;br /&gt;
as &amp;quot;nearly static&amp;quot;) is &amp;lt;math&amp;gt;R&amp;lt;/math&amp;gt;, the Mu &amp;lt;i&amp;gt;trapping rate&amp;lt;/i&amp;gt; &lt;br /&gt;
(defined in this vague way) is some &amp;quot;rate constant&amp;quot; &amp;lt;math&amp;gt;k&amp;lt;/math&amp;gt; &lt;br /&gt;
times the defect concentration &amp;lt;math&amp;gt;c&amp;lt;/math&amp;gt;: &lt;br /&gt;
&amp;lt;center&amp;gt;&amp;lt;math&amp;gt; \Lambda = kc = 4 \pi c R D ,&amp;lt;/math&amp;gt;&amp;lt;/center&amp;gt;&lt;br /&gt;
giving&lt;br /&gt;
&amp;lt;center&amp;gt;&amp;lt;math&amp;gt; k = { \pi R a^2 \over \tau_i } .  &lt;br /&gt;
&amp;lt;/math&amp;gt;&amp;lt;/center&amp;gt;&lt;br /&gt;
Meanwhile if a weak longitudinal field (wLF) of &amp;lt;math&amp;gt;B&amp;lt;/math&amp;gt; is applied, &lt;br /&gt;
the relaxation rate in state &amp;lt;math&amp;gt;\vert i \rangle&amp;lt;/math&amp;gt; is given by &lt;br /&gt;
&amp;lt;center&amp;gt;&amp;lt;math&amp;gt;&lt;br /&gt;
 \lambda_i = { 2 \delta^2 \tau_i \over 1 + \omega^2 \tau_i^2 }&lt;br /&gt;
&amp;lt;/math&amp;gt;&amp;lt;/center&amp;gt;&lt;br /&gt;
where &amp;lt;math&amp;gt;\delta&amp;lt;/math&amp;gt; is the static dipolar width (which can sometimes &lt;br /&gt;
be determined directly from wTF\ measurements in the static limit) &lt;br /&gt;
and &amp;lt;math&amp;gt;\omega = \gamma_{\rm Mu} B&amp;lt;/math&amp;gt; is the muonium Larmor frequency (I assume &lt;br /&gt;
the low-field limit where hyperfine splittings can be neglected).  &lt;br /&gt;
&lt;br /&gt;
Once trapped, the Mu still hops slowly.  Of course it hops at &lt;br /&gt;
different rates when trapped at different &amp;quot;depths&amp;quot; in the &lt;br /&gt;
strain fields, but I shall just pretend for now that the hopping &lt;br /&gt;
around in the strain field can be characterized by a slow hop rate &lt;br /&gt;
&amp;lt;math&amp;gt;\tau_f^{-1}&amp;lt;/math&amp;gt; in the state &amp;lt;math&amp;gt;\vert f \rangle&amp;lt;/math&amp;gt; &lt;br /&gt;
[trapped state].  Then the final &lt;br /&gt;
state relaxation rate is &lt;br /&gt;
&amp;lt;center&amp;gt;&amp;lt;math&amp;gt;&lt;br /&gt;
 \lambda_f = { 2 \delta^2 \tau_f \over 1 + \omega^2 \tau_f^2 } , &lt;br /&gt;
&amp;lt;/math&amp;gt;&amp;lt;/center&amp;gt;&lt;br /&gt;
where I have tacitly assumed that &amp;lt;math&amp;gt;\delta&amp;lt;/math&amp;gt; is the same in both &lt;br /&gt;
states [&amp;lt;math&amp;gt;\vert i \rangle&amp;lt;/math&amp;gt; and &amp;lt;math&amp;gt;\vert f \rangle&amp;lt;/math&amp;gt;] &lt;br /&gt;
because &amp;lt;math&amp;gt;R \gg a&amp;lt;/math&amp;gt; and the Mu atom &lt;br /&gt;
always sees the same types of neighbours.  &lt;br /&gt;
&lt;br /&gt;
Then, in principle, the relaxation function depends only upon &lt;br /&gt;
&amp;lt;math&amp;gt;\tau_i&amp;lt;/math&amp;gt;, &amp;lt;math&amp;gt;\tau_f&amp;lt;/math&amp;gt;, &amp;lt;math&amp;gt;R&amp;lt;/math&amp;gt; &lt;br /&gt;
and the known or (sometimes) independently measurable parameters &lt;br /&gt;
&amp;lt;math&amp;gt;c&amp;lt;/math&amp;gt;, &amp;lt;math&amp;gt;a&amp;lt;/math&amp;gt;, &amp;lt;math&amp;gt;B&amp;lt;/math&amp;gt; and &amp;lt;math&amp;gt;\delta&amp;lt;/math&amp;gt;.  &lt;br /&gt;
It may or may not be worth fitting &lt;br /&gt;
the data directly to this formula with &lt;br /&gt;
&amp;lt;math&amp;gt;\tau_i&amp;lt;/math&amp;gt;, &amp;lt;math&amp;gt;\tau_f&amp;lt;/math&amp;gt; and &amp;lt;math&amp;gt;R&amp;lt;/math&amp;gt; as free parameters.  &lt;br /&gt;
&lt;br /&gt;
== Phase Shifts in Precession Experiments ==&lt;br /&gt;
&lt;br /&gt;
The conventional way to represent &amp;lt;i&amp;gt;precession&amp;lt;/i&amp;gt; &lt;br /&gt;
in transverse field is to let &amp;lt;math&amp;gt;\tilde{P}^\mu(t)&amp;lt;/math&amp;gt; be a &amp;lt;i&amp;gt;complex&amp;lt;/i&amp;gt; &lt;br /&gt;
muon polarization whose real part is the projection of &lt;br /&gt;
&amp;lt;math&amp;gt;\vec{P}^\mu(t)&amp;lt;/math&amp;gt; along its initial direction (assumed &lt;br /&gt;
perpendicular to the applied field) and whose imaginary &lt;br /&gt;
part is the projection along the orthogonal axis -- &amp;lt;i&amp;gt;e.g.&amp;lt;/i&amp;gt;, if &lt;br /&gt;
&amp;lt;math&amp;gt;\vec{B} \parallel \hat{z}&amp;lt;/math&amp;gt; and &lt;br /&gt;
&amp;lt;math&amp;gt;\vec{P}^\mu(0) \parallel \hat{x}&amp;lt;/math&amp;gt;, &lt;br /&gt;
&amp;lt;math&amp;gt;\tilde{P}(t) \equiv P^\mu_x(t) + i P^\mu_y(t)&amp;lt;/math&amp;gt;.  &lt;br /&gt;
&lt;br /&gt;
If we replace &amp;lt;math&amp;gt;\lambda_i&amp;lt;/math&amp;gt; and/or &amp;lt;math&amp;gt;\lambda_f&amp;lt;/math&amp;gt; with &lt;br /&gt;
&amp;lt;math&amp;gt;\kappa_i = \lambda_i - i \omega_i&amp;lt;/math&amp;gt; or &amp;lt;math&amp;gt;\kappa_f = &lt;br /&gt;
\lambda_f - i \omega_f&amp;lt;/math&amp;gt;,&lt;br /&gt;
so that the argument of the exponential function &lt;br /&gt;
has an &amp;lt;i&amp;gt;imaginary part&amp;lt;/i&amp;gt;, &lt;br /&gt;
then the description given earlier covers TF-&amp;amp;micro;SR or wTF-MSR &lt;br /&gt;
precession experiments -- &amp;lt;i&amp;gt;e.g.&amp;lt;/i&amp;gt;, for Mu &amp;lt;math&amp;gt;\to&amp;lt;/math&amp;gt; &lt;br /&gt;
diamagnetic compound in wTF\ muonium chemistry, for &lt;br /&gt;
&amp;lt;math&amp;gt;F^+ \to F^-&amp;lt;/math&amp;gt; hyperfine states of muonic atoms &lt;br /&gt;
or for &amp;lt;math&amp;gt;\mu^+ \to&amp;lt;/math&amp;gt; Sn traps in Sb.  Equation (\ref{eq:GeneralRateEq}) &lt;br /&gt;
is unchanged, but since &amp;lt;math&amp;gt;\kappa_i&amp;lt;/math&amp;gt; and/or &amp;lt;math&amp;gt;\kappa_f&amp;lt;/math&amp;gt; &lt;br /&gt;
are complex, the prefactors in front of the time-dependent &lt;br /&gt;
terms are also complex and therefore include &amp;lt;i&amp;gt;phase shifts}.  &lt;br /&gt;
Although this extension is formally trivial, it introduces &lt;br /&gt;
a wealth of additional phenomenology.  &lt;br /&gt;
&lt;br /&gt;
In the first two examples outlined briefly below, &lt;br /&gt;
the &amp;lt;i&amp;gt;exponential relaxation&amp;lt;/i&amp;gt; &amp;lt;math&amp;gt;(e^{- \lambda t})&amp;lt;/math&amp;gt; &lt;br /&gt;
picture used to derive the General Rate Equation is replaced &lt;br /&gt;
by a &amp;lt;i&amp;gt;pure precession&amp;lt;/i&amp;gt; picture &amp;lt;math&amp;gt;(e^{i \omega t})&amp;lt;/math&amp;gt; &lt;br /&gt;
with &amp;lt;i&amp;gt;no&amp;lt;/i&amp;gt; relaxation -- that is, &amp;lt;math&amp;gt;(-\lambda \to i \omega)&amp;lt;/math&amp;gt;.  &lt;br /&gt;
Relaxation can be re-introduced by allowing &amp;lt;math&amp;gt;\omega&amp;lt;/math&amp;gt; to have &lt;br /&gt;
a positive imaginary component.  For simplicity we will &lt;br /&gt;
restrict ourselves to low magnetic field where muonium &lt;br /&gt;
precession can be approximated by a single frequency &lt;br /&gt;
&amp;lt;math&amp;gt;\omega_{\rm Mu} = - \gamma_{\rm Mu} B&amp;lt;/math&amp;gt; (where &amp;lt;math&amp;gt;H&amp;lt;/math&amp;gt; is the &lt;br /&gt;
applied transverse field) and is in the opposite sense &lt;br /&gt;
to the diamagnetic precession signal at the much lower &lt;br /&gt;
frequency &amp;lt;math&amp;gt;\omega_\mu = \gamma_\mu B&amp;lt;/math&amp;gt;.  &lt;br /&gt;
(Both magnetogyric ratios &amp;lt;math&amp;gt;\gamma&amp;lt;/math&amp;gt; are taken to be positive &lt;br /&gt;
constants.)  &lt;br /&gt;
&lt;br /&gt;
=== Fast-Reacting Muonium ===&lt;br /&gt;
&lt;br /&gt;
The oldest application of this model is to the &lt;br /&gt;
&amp;lt;i&amp;gt;residual polarization&amp;lt;/i&amp;gt; in a system where &lt;br /&gt;
muons differentiate at &amp;lt;math&amp;gt;t=0&amp;lt;/math&amp;gt; into &lt;br /&gt;
a &amp;quot;prompt&amp;quot; diamagnetic fraction &amp;lt;math&amp;gt;f_D&amp;lt;/math&amp;gt; &lt;br /&gt;
and an initial muonium fraction &amp;lt;math&amp;gt;f_{\rm Mu}&amp;lt;/math&amp;gt;.  &lt;br /&gt;
(We will neglect any &amp;quot;missing polarization&amp;quot; &lt;br /&gt;
as this enters simply as an overall reduction of all amplitudes.)  &lt;br /&gt;
The Mu fraction &amp;lt;i&amp;gt;reacts chemically&amp;lt;/i&amp;gt; with reagent &amp;quot;X&amp;quot; &lt;br /&gt;
&amp;lt;center&amp;gt;Mu + X &amp;lt;math&amp;gt;\to&amp;lt;/math&amp;gt; MuX &amp;lt;/center&amp;gt;&lt;br /&gt;
at exponentially distributed times (rate &amp;lt;math&amp;gt;\Lambda&amp;lt;/math&amp;gt;) &lt;br /&gt;
to form a &amp;quot;delayed&amp;quot; diamagnetic fraction which is &lt;br /&gt;
reduced in magnitude and rotated in phase due to the &lt;br /&gt;
fast precession of Mu prior to chemical reaction.  &lt;br /&gt;
In strong magnetic fields where the Mu hyperfine splitting &lt;br /&gt;
becomes important, this can be somewhat more complicated; &lt;br /&gt;
and if the reaction rate &amp;lt;math&amp;gt;\Lambda&amp;lt;/math&amp;gt; is fast enough to compete &lt;br /&gt;
with the Mu hyperfine frequency &amp;lt;math&amp;gt;\omega_0 \approx 4.463&amp;lt;/math&amp;gt; GHz itself, then &lt;br /&gt;
complications again arise; but for low fields and modest &lt;br /&gt;
reaction rates we may treat the evolution of the muon spin &lt;br /&gt;
in Mu as a simple precession with frequency &lt;br /&gt;
&amp;lt;math&amp;gt;\omega_{\rm Mu} = - \gamma_{\rm Mu} B&amp;lt;/math&amp;gt; &lt;br /&gt;
(in the opposite sense to the diamagnetic precession at &lt;br /&gt;
&amp;lt;math&amp;gt;\omega_\mu = + \gamma_\mu B&amp;lt;/math&amp;gt;) and the effect of &lt;br /&gt;
&amp;quot;hyperfine oscillations&amp;quot; can be treated as a simple &lt;br /&gt;
loss of half the muon polarization in Mu.  &lt;br /&gt;
In that case we can simply replace &lt;br /&gt;
&amp;lt;math&amp;gt;-\lambda_i&amp;lt;/math&amp;gt; by &amp;lt;math&amp;gt;-\gamma_{\rm Mu} B&amp;lt;/math&amp;gt; and &lt;br /&gt;
&amp;lt;math&amp;gt;-\lambda_f&amp;lt;/math&amp;gt; by &amp;lt;math&amp;gt;+\gamma_\mu B&amp;lt;/math&amp;gt; &lt;br /&gt;
in the General Rate Equation, giving &lt;br /&gt;
&amp;lt;center&amp;gt;&amp;lt;math&amp;gt;&lt;br /&gt;
 \tilde{P}_{\rm res} = {1 \over 2} {\Lambda \over \Lambda &lt;br /&gt;
 - i(\gamma_{\rm Mu} + \gamma_\mu) B }&lt;br /&gt;
&amp;lt;/math&amp;gt;&amp;lt;/center&amp;gt;&lt;br /&gt;
which adds to the original diamagnetic component to give a &lt;br /&gt;
&amp;lt;i&amp;gt;diamagnetic signal&amp;lt;/i&amp;gt; &lt;br /&gt;
&amp;lt;center&amp;gt;&amp;lt;math&amp;gt;&lt;br /&gt;
 \tilde{P}_D(t) = \left[ f_D + \tilde{P}_{\rm res} \right] &lt;br /&gt;
 e^{i \gamma_\mu B t} .  &lt;br /&gt;
&amp;lt;/math&amp;gt;&amp;lt;/center&amp;gt;&lt;br /&gt;
&lt;br /&gt;
=== Delayed Muonium Formation ===&lt;br /&gt;
&lt;br /&gt;
The opposite situation (in a sense) applies in some insulators and semicondustors &lt;br /&gt;
where the muon ensemble differentiates initially into &lt;br /&gt;
a &amp;lt;i&amp;gt;stable&amp;lt;/i&amp;gt; diamagnetic fraction &amp;lt;math&amp;gt;f_D&amp;lt;/math&amp;gt;, &lt;br /&gt;
a &amp;lt;i&amp;gt;stable&amp;lt;/i&amp;gt; muonium fraction &amp;lt;math&amp;gt;f_{\rm Mu}&amp;lt;/math&amp;gt; &lt;br /&gt;
and an &amp;lt;i&amp;gt;unstable&amp;lt;/i&amp;gt; diamagnetic fraction &amp;lt;math&amp;gt;f_X&amp;lt;/math&amp;gt; &lt;br /&gt;
which captures an electron at exponentially distributed &lt;br /&gt;
times (rate &amp;lt;math&amp;gt;\Lambda&amp;lt;/math&amp;gt;) to form &amp;lt;i&amp;gt;delayed muonium&amp;lt;/i&amp;gt;: &lt;br /&gt;
&amp;lt;center&amp;gt;&amp;lt;math&amp;gt; \mu^+ + e^- \to &amp;lt;/math&amp;gt; Mu&amp;lt;/center&amp;gt;&lt;br /&gt;
where the free electron presumably comes from &lt;br /&gt;
the incoming muon&amp;#039;s ionization track.  &lt;br /&gt;
(This can only work in systems with substantial &amp;lt;math&amp;gt;e^-&amp;lt;/math&amp;gt; mobilities.)  &lt;br /&gt;
In this case there are two detectable precessing components, &lt;br /&gt;
the &amp;lt;i&amp;gt;diamagnetic signal&amp;lt;/i&amp;gt; &lt;br /&gt;
&amp;lt;center&amp;gt;&amp;lt;math&amp;gt;&lt;br /&gt;
 \tilde{P}_D(t) = \left[ f_D + f_X \left( 1 - {1 \over 2} &lt;br /&gt;
 { \Lambda \over \Lambda - i(\gamma_\mu + \gamma_{\rm Mu}) B } &lt;br /&gt;
 \right) e^{-\Lambda t} \right] e^{i \gamma_\mu B t} &lt;br /&gt;
&amp;lt;/math&amp;gt;&amp;lt;/center&amp;gt;&lt;br /&gt;
and the &amp;lt;i&amp;gt;muonium signal&amp;lt;/i&amp;gt; (in low field) &lt;br /&gt;
&amp;lt;center&amp;gt;&amp;lt;math&amp;gt;&lt;br /&gt;
\tilde{P}_{\rm Mu}(t) = {1 \over 2} \left[ f_{\rm Mu} + f_X &lt;br /&gt;
 { \Lambda \over \Lambda - i(\gamma_\mu + \gamma_{\rm Mu}) B } &lt;br /&gt;
 \right] e^{-i \gamma_{\rm Mu} B t} .  &lt;br /&gt;
&amp;lt;/math&amp;gt;&amp;lt;/center&amp;gt;&lt;br /&gt;
In this case &amp;lt;i&amp;gt;both&amp;lt;/i&amp;gt; components (D and Mu) &lt;br /&gt;
show a phase shift in general &lt;br /&gt;
and the reaction rate can in many cases be measured directly &lt;br /&gt;
from the decaying component of the diamagnetic signal.  &lt;br /&gt;
Here I have neglected any &amp;lt;i&amp;gt;relaxation&amp;lt;/i&amp;gt; in either the &lt;br /&gt;
initial or the final states; this can be put in easily enough, &lt;br /&gt;
just by letting the frequencies be complex: &lt;br /&gt;
&amp;lt;math&amp;gt;\exp(i \omega t) \to \exp(i [\omega + i \lambda]t)&amp;lt;/math&amp;gt;.  &lt;br /&gt;
&lt;br /&gt;
&amp;lt;center&amp;gt;&lt;br /&gt;
[[Image:DMF_0-400ns.png|600px|inline image (click to see full size)]]&lt;br /&gt;
{| width=&amp;quot;80%&amp;quot; &lt;br /&gt;
! align=&amp;quot;left&amp;quot; |&lt;br /&gt;
Figure &amp;lt;b&amp;gt;3a&amp;lt;/b&amp;gt;:  &lt;br /&gt;
First 400 ns of muon polarization functions for &lt;br /&gt;
delayed muonium formation (&amp;lt;math&amp;gt;q=0.5&amp;lt;/math&amp;gt;) &lt;br /&gt;
in an applied magnetic field of 20 G:  &lt;br /&gt;
a non-relaxing initial diamagnetic fraction &lt;br /&gt;
captures radiolysis electrons to &lt;br /&gt;
form muonium at rates &amp;lt;math&amp;gt;\Lambda = \{0,1,3,7,20\}&amp;lt;/math&amp;gt; &amp;amp;micro;s&amp;lt;math&amp;gt;^{-1}&amp;lt;/math&amp;gt; &lt;br /&gt;
after which Mu relaxes at 0.1 &amp;amp;micro;s&amp;lt;math&amp;gt;{-1}&amp;lt;/math&amp;gt;.  &lt;br /&gt;
Only the real part of the polarization is shown.  &lt;br /&gt;
|}&amp;lt;/center&amp;gt;&amp;lt;center&amp;gt;&lt;br /&gt;
[[Image:DMF_0-4us.png|600px|inline image (click to see full size)]]&lt;br /&gt;
{| width=&amp;quot;80%&amp;quot; &lt;br /&gt;
! align=&amp;quot;left&amp;quot; |&lt;br /&gt;
Figure &amp;lt;b&amp;gt;3b&amp;lt;/b&amp;gt;:  &lt;br /&gt;
First 4 &amp;amp;micro;s of the same muon polarization functions as in Fig. &amp;lt;b&amp;gt;3a&amp;lt;/b&amp;gt;&lt;br /&gt;
}&lt;br /&gt;
|}&amp;lt;/center&amp;gt;&lt;br /&gt;
&lt;br /&gt;
&amp;lt;center&amp;gt;&lt;br /&gt;
[[Image:DMF_0.5G.png|600px|inline image (click to see full size)]]&lt;br /&gt;
{| width=&amp;quot;80%&amp;quot; &lt;br /&gt;
! align=&amp;quot;left&amp;quot; |&lt;br /&gt;
Figure &amp;lt;b&amp;gt;4&amp;lt;/b&amp;gt;:  &lt;br /&gt;
Muon polarization functions for &lt;br /&gt;
delayed muonium formation (&amp;lt;math&amp;gt;q=0.5&amp;lt;/math&amp;gt;) &lt;br /&gt;
in an applied magnetic field of 0.5 G:  &lt;br /&gt;
a non-relaxing initial diamagnetic fraction &lt;br /&gt;
captures radiolysis electrons to &lt;br /&gt;
form non-relaxing muonium at rates &lt;br /&gt;
&amp;lt;math&amp;gt;\Lambda = \{0.5,1,3,7,20,100\}&amp;lt;/math&amp;gt; &amp;amp;micro;s&amp;lt;math&amp;gt;^{-1}&amp;lt;/math&amp;gt;.  &lt;br /&gt;
Only the real part of the polarization is shown.  &lt;br /&gt;
Note the obvious phase shifts of the Mu signal &lt;br /&gt;
due to delayed formation.  &lt;br /&gt;
|}&amp;lt;/center&amp;gt;&lt;br /&gt;
&lt;br /&gt;
=== General Use with Fourier Transforms ===&lt;br /&gt;
&lt;br /&gt;
The complex formulation allows treatment of yet more general cases &lt;br /&gt;
in which the time dependence of the muon polarization in &lt;br /&gt;
&amp;lt;math&amp;gt;\vert i \rangle&amp;lt;/math&amp;gt; or &amp;lt;math&amp;gt;\vert f \rangle&amp;lt;/math&amp;gt; &lt;br /&gt;
is non-exponential, using the following procedure:  &lt;br /&gt;
&lt;br /&gt;
(1) If the Fourier transform of &amp;lt;math&amp;gt;\tilde{P}_i(t)&amp;lt;/math&amp;gt; &lt;br /&gt;
or &amp;lt;math&amp;gt;\tilde{P}_f(t)&amp;lt;/math&amp;gt; contains &lt;br /&gt;
&amp;lt;i&amp;gt;negative frequency components&amp;lt;/i&amp;gt;, most FFT algorithms will get &lt;br /&gt;
confused; to avoid this, first &amp;lt;i&amp;gt;transform into a rotating &lt;br /&gt;
reference frame&amp;lt;/i&amp;gt; (RRF) at frequency &amp;lt;math&amp;gt;\omega_0&amp;lt;/math&amp;gt;: &lt;br /&gt;
&amp;lt;center&amp;gt;&amp;lt;math&amp;gt;&lt;br /&gt;
\tilde{P}_i^{\scriptscriptstyle\rm RRF}(t) = \tilde{P}_i(t) \cdot e^{i \omega_0 t} &amp;lt;/math&amp;gt;&amp;lt;/center&amp;gt;&lt;br /&gt;
and &amp;lt;center&amp;gt;&amp;lt;math&amp;gt;&lt;br /&gt;
\tilde{P}_f^{\scriptscriptstyle\rm RRF}(t) = \tilde{P}_f(t) \cdot e^{i \omega_0 t} .  &lt;br /&gt;
&amp;lt;/math&amp;gt;&amp;lt;/center&amp;gt;&lt;br /&gt;
&lt;br /&gt;
(2) Next, Fourier transform &amp;lt;math&amp;gt;\tilde{P}_i^{\scriptscriptstyle\rm RRF}(t)&amp;lt;/math&amp;gt; &lt;br /&gt;
and &amp;lt;math&amp;gt;\tilde{P}_f^{\scriptscriptstyle\rm RRF}(t)&amp;lt;/math&amp;gt; &lt;br /&gt;
to obtain their frequency components &amp;lt;math&amp;gt;a(\omega)&amp;lt;/math&amp;gt;: &lt;br /&gt;
&amp;lt;center&amp;gt;&amp;lt;math&amp;gt;&lt;br /&gt;
\tilde{P}_i^{\scriptscriptstyle\rm RRF}(t) = &lt;br /&gt;
\int_0^\infty a^{\scriptscriptstyle\rm RRF}_i(\omega) e^{i \omega t} d\omega &lt;br /&gt;
&amp;lt;/math&amp;gt;&amp;lt;/center&amp;gt; and &amp;lt;center&amp;gt;&amp;lt;math&amp;gt;&lt;br /&gt;
\tilde{P}_f^{\scriptscriptstyle\rm RRF}(t) = &lt;br /&gt;
\int_0^\infty a^{\scriptscriptstyle\rm RRF}_f(\omega) e^{i \omega t} d\omega &lt;br /&gt;
&amp;lt;/math&amp;gt;&amp;lt;/center&amp;gt;&lt;br /&gt;
&lt;br /&gt;
(3) Then some simple calculus produces the residual polarization in the RRF, &lt;br /&gt;
&amp;lt;center&amp;gt;&amp;lt;math&amp;gt;&lt;br /&gt;
\tilde{P}^{\scriptscriptstyle\rm RRF}(t) = &lt;br /&gt;
e^{-\Lambda t} \tilde{P}_i^{\scriptscriptstyle\rm RRF}(t) &lt;br /&gt;
 + \Lambda \int_0^\infty d\omega a^{\scriptscriptstyle\rm RRF}_i(\omega) &lt;br /&gt;
  \int_0^\infty d\omega&amp;#039; a^{\scriptscriptstyle\rm RRF}_f(\omega&amp;#039;) \left[ { &lt;br /&gt;
  e^{-\Lambda t} \cdot e^{i \omega t} - e^{i \omega&amp;#039; t} &lt;br /&gt;
 \over i(\omega - \omega&amp;#039;) - \Lambda} \right] .  &lt;br /&gt;
&amp;lt;/math&amp;gt;&amp;lt;/center&amp;gt;&lt;br /&gt;
&lt;br /&gt;
(4) Finally, transform the result back into the lab frame: &lt;br /&gt;
&amp;lt;center&amp;gt;&amp;lt;math&amp;gt;&lt;br /&gt;
\tilde{P}(t) = \tilde{P}^{\scriptscriptstyle\rm RRF}(t) \cdot e^{-i \omega_0 t} .  &lt;br /&gt;
&amp;lt;/math&amp;gt;&amp;lt;/center&amp;gt;&lt;/div&gt;</summary>
		<author><name>WikiSysop</name></author>
	</entry>
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